Open Access Pub publishes peer-reviewed, free-to-read open-access articles. Showing
articles matching Oxygen reduction reaction — open any to read the full text,
or download the PDF or XML.
Kejian DengCorresponding author Key Laboratory of Catalysis and Materials Sciences of the State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, Wuhan, 430074, Hubei, China
In order to distinguish the roles of four types of nitrogen species in oxygen reduction reaction, the ketoamine condensation reactions between the ketone group of graphene oxide and amidogen of aniline and o-phenylenediamine were employed to generate –C=N- bond at the edge of graphene nanoplatelets, and then nitrogen-doped graphene nanoplatelets with pyrrolic N, pyridinic N and pyridinic N+-O- rather than graphitic nitrogen were obtained by post thermal treatments. The resulting catalysts were characterized by X-ray diffraction analysis, X-ray photoelectron spectroscopy and electrochemical measurements. It is found that edge-selectively nitrogen-doped graphene nanopaltelets with nitrogen content of up to 4.28 atom% have been prepared. Nitrogen doping helps to improve activity of oxygen reduction reaction slightly, suggesting nitrogen doping at the edge of graphene does not contribute a lot to the enhancement of activity.